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Demulsifier

A demulsifier is a surface-active chemical injected into crude oil at parts-per-million levels to displace the natural films that stabilise water droplets. With the films weakened, droplets can merge and settle. It works together with heat, time and electrostatic fields.

Also written as: emulsion breaker

Demulsifier explained

Demulsifiers are blended for a particular crude and selected by bottle test. Injection point matters: the chemical needs mixing and time upstream of the vessel. Overdosing can stabilise an emulsion instead of breaking it.

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Emulsion (water-in-oil)
A water-in-oil emulsion is a dispersion of small water droplets in crude oil, held apart by natural surface-active films of asphaltenes, resins, waxes and fine solids. The droplets will not settle until those films are broken and the droplets merge.
Electrostatic coalescer
An electrostatic coalescer is a pressure vessel with energised electrode grids, in which a high-voltage field coalesces water droplets in crude oil so they settle. Used without wash water it is a dehydrator; with wash water it is a desalter.
Crude oil desalter
A crude oil desalter is an electrostatic coalescer operated with wash water mixed into the crude upstream. The water dilutes the salty droplets in the crude, and the coalescer then removes the water and most of the salt with it.
Crude oil dehydrator
A crude oil dehydrator is an electrostatic coalescer that removes produced water from crude oil to meet a water specification, usually stated as basic sediment and water. No wash water is added. It is the same equipment as a desalter.
Wash water
Wash water is low-salinity water injected into crude oil upstream of a desalter to dilute the salty water droplets it carries. It is typically added at 3 to 10 per cent of the crude volume, then removed in the desalter.
Mixing valve
A mixing valve is a throttling valve upstream of a desalter that shears wash water into fine droplets so they meet the salty water in the crude. Its pressure drop balances mixing against making an emulsion too tight to break.

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