Crude oil treatment

Electrostatic coalescer prewash

An electrostatic coalescer prewash removes entrained caustic from kerosene after the caustic prewash of a kerosene sweetening unit. A high-voltage direct current (DC) field makes the fine caustic droplets merge and settle, so the kerosene reaches the sweetening reactor with its aqueous content reduced to parts per million. Axsia Howmar designs new units and supports installed ones.

Typical electrode voltage, sustained because kerosene has very low conductivity
20 to 40 kV DC
Aqueous phase left in the treated kerosene, set per project
ppm level
Vertical or horizontal vessel, delivered with piping and local control panel
Skid-mounted

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How it works: Electrostatic coalescer prewash

  1. Kerosene arrives from the prewash contactor

    The caustic prewash has removed hydrogen sulphide and naphthenic acids. The kerosene now carries a fine, stable dispersion of spent caustic.

  2. The inlet distributor spreads the flow

    Kerosene enters below the electrode grid and above the caustic interface through a low-pressure-drop distributor, so it rises evenly and does not disturb the settled caustic.

  3. The DC field makes droplets merge

    A high-voltage DC field across the electrode grid polarises the caustic droplets. Neighbouring droplets attract, collide and merge into larger ones.

  4. Enlarged droplets settle

    The larger droplets fall against the rising kerosene and join the caustic layer at the bottom of the vessel.

  5. Caustic is drawn off on interface control

    An interface level controller returns the settled caustic to the caustic circuit.

  6. Treated kerosene goes to the sweetening reactor

    Kerosene leaves through an outlet collector at the top of the vessel.

The sweetening unit

Where the prewash coalescer sits in a kerosene sweetening unit

Jet fuel and kerosene are sweetened in a mercaptan oxidation unit, most commonly the UOP Merox process. The kerosene first passes through a caustic prewash, where sodium hydroxide reacts with hydrogen sulphide (NaOH + H2S gives NaSH + H2O) and neutralises the naphthenic acids to form sodium naphthenates. It then enters the reactor, where mercaptans are oxidised to disulphides over a caustic-wetted catalyst bed with compressed air (4RSH + O2 gives 2RSSR + 2H2O). Water wash, salt bed and clay bed finish the product.

The prewash leaves a fine, stable dispersion of spent caustic and sodium naphthenate in the kerosene. The naphthenates act as surfactants, so the droplets do not settle by gravity in the time available. If they reach the reactor they foul the catalyst bed, consume fresh caustic, raise the sodium in the product and put the haze and water-separation specifications at risk. The electrostatic prewash coalescer sits between the prewash and the reactor to remove them.

Simplified flow of a kerosene sweetening unit: caustic prewash with coalescer section, reactor with caustic settler, then water wash, salt bed and clay bed.
Simplified flow of a kerosene sweetening unit: caustic prewash with coalescer section, reactor with caustic settler, then water wash, salt bed and clay bed.

DC electrostatic coalescer

A DC field takes the spent caustic and sodium naphthenate out of the kerosene

The coalescer is a pressure vessel with a vertical electrode array held on PTFE insulators above the caustic interface. A three-phase low-voltage supply is stepped up and rectified in the power unit to a steady direct current output of 20,000 to 40,000 volts, carried through a PTFE-insulated high-pressure bushing to the electrodes. A field of this strength can be held continuously because kerosene has very low electrical conductivity.

Kerosene enters through a low-pressure-drop distributor below the electrodes and rises through the field. The DC field polarises and charges the droplets of spent caustic and sodium naphthenate; they attract, collide and merge into drops large enough to settle against the flow to the caustic layer at the bottom of the vessel, from where they are drawn off on interface control and returned to the caustic circuit. Treated kerosene leaves through the outlet collector at the top with its aqueous phase reduced to parts per million, ready for the reactor.

The power unit is fully reactive, so it limits its own current when the electrodes see conductive liquid and stays on line through upsets, and a voltage controller on the local panel lets the operator set the electrode voltage across the full range.

3D model of a skid-mounted vertical DC electrostatic prewash coalescer: vessel with top platform and power unit, high-voltage bushing, level bridles and interface instruments, caustic draw-off and local control panel.
3D model of a skid-mounted vertical DC electrostatic prewash coalescer: vessel with top platform and power unit, high-voltage bushing, level bridles and interface instruments, caustic draw-off and local control panel.

Built as a package

Assembled and tested before it leaves the workshop

A prewash coalescer is a relatively small unit, so it is supplied as a complete skid: vessel, power unit and local control panel, high-pressure bushing, interface level instruments, caustic draw-off and product piping, all mounted on one frame. The electrical system is high-voltage tested and the skid pressure tested at the fabricator, under our inspection and test plan, before despatch.

On site the package needs foundations, a power supply and the process tie-ins, which keeps the shutdown window for installation short.

Skid-mounted horizontal electrostatic coalescer package at the fabricator: vessel, top-mounted power unit, control panel and skid piping assembled for testing.
Skid-mounted horizontal electrostatic coalescer package at the fabricator: vessel, top-mounted power unit, control panel and skid piping assembled for testing.

In service

Operating on refinery kerosene sweetening units

Electrostatic prewash coalescers of this design run on kerosene sweetening units in European refineries, in both horizontal and vertical configuration. A horizontal vessel gives a long settling path and a large interface area at low height; a vertical vessel suits a tight plot. Our engineers have designed, commissioned and supported units of both types, and support existing installations, including units built by others, with troubleshooting, retrofit internals and spare parts.

Horizontal electrostatic coalescer installed on a refinery kerosene sweetening unit, with access platform, power unit and local control panel.
Horizontal electrostatic coalescer installed on a refinery kerosene sweetening unit, with access platform, power unit and local control panel.

Beyond kerosene

The same DC coalescer for other low-conductivity products

Because the DC field depends on the product being a poor conductor, the same coalescer design dehydrates or removes aqueous treating solutions from gas condensate, liquefied petroleum gas (LPG), naphtha, jet fuel and diesel, and can be applied on the caustic settling side of a sweetening reactor. Units are supplied vertical or horizontal and, being relatively small, are usually delivered as skid-mounted packages with piping and a local control panel for quick site tie-in.

Where the prewash coalescer sits in the process

The prewash coalescer sits between the caustic prewash contactor and the mercaptan oxidation (sweetening) reactor of a kerosene treating unit. The prewash removes hydrogen sulphide and naphthenic acids. The coalescer then removes the spent caustic that the kerosene carries out of the contactor, so that the reactor receives kerosene and not a caustic dispersion. It is the same electrostatic principle as the electrostatic coalescers used on crude oil, applied to a clean, low-conductivity product.

Why inlet distribution decides performance

Turbulence and uneven flow at the inlet are the main threats to a prewash coalescer. A jet of kerosene that channels through one part of the electrode grid shortens residence time there, lifts caustic that has already settled, and leaves the rest of the field under-used. Axsia Howmar designs the inlet distributor and outlet collector with a computational fluid dynamics (CFD) model of the whole vessel. The model is iterated until it shows:

  • uniform upward velocity across the full cross-section of the electrode grid;
  • no short-circuiting from inlet to outlet;
  • droplet settling paths that reach the interface at design flow and at turndown;
  • no disturbance of the settled caustic layer;
  • pressure drop across the distributor and collector within the allowance.

On a retrofit the existing vessel and nozzles are modelled first, so new internals are designed against the flow field the plant actually has.

Design of the main components

Separation depends on how the components work together, so they are designed as one system.

  • Power unit. A three-phase low-voltage supply is stepped up and rectified to a steady DC output. A reactive design limits the current drawn during an upset, so the unit stays on line. A voltage controller on the local panel lets the operator set the electrode voltage.
  • Entrance bushing. The entrance bushing carries the high-voltage supply through the vessel wall to the electrode grid. It is rated for the design pressure and temperature of the prewash service.
  • Electrode grid. The size, orientation and position of the grid in the vessel are set for the caustic-in-kerosene duty, with an open flow path through the field.
  • Fluid distribution. The inlet is below the grid and above the normal interface. The outlet collector gives an even draw-off.
  • Hazardous area. Electrical equipment is certified for the area classification of the unit location.

Support for installed coalescers and precipitators

Many kerosene treating units run electrostatic coalescers or precipitators supplied decades ago, often by a manufacturer that has closed or been absorbed. Axsia Howmar supports these units in three ways.

  • Assessment and retrofit. Replacement electrode grid and insulators sized to the existing shell, entrance bushings matched to existing nozzles, a new power unit with voltage control, and distributor and collector upgrades designed from a CFD model of the existing vessel. An ageing precipitator or settler can be converted to a DC coalescer.
  • Troubleshooting. Caustic carryover, power unit trips, low field voltage and interface problems usually trace to a small number of electrical, process or mechanical causes. See troubleshooting and performance diagnostics.
  • Spare parts. Entrance bushings, grid insulators, grid assemblies and hangers, power units and controllers, and distributor internals. Where the original part cannot be obtained, a replacement is engineered from drawings or from the worn part. See prewash coalescer spare parts and legacy equipment spare parts. Parts for equipment built by others are supplied as suitable for that equipment and are not original manufacturer parts unless our quotation says so.

What we look at first on an existing unit

  • Vessel dimensions, design pressure (barg) and temperature, nozzle schedule and orientation.
  • Original manufacturer, model and year, and the documentation that survives.
  • Electrode grid type and condition; insulator and entrance bushing materials.
  • Power unit rating, output voltage and controller type.
  • Design and current throughput, kerosene properties and caustic strength.
  • Interface level control and caustic draw-off routing.
  • Hazardous area classification of the unit location.
  • Symptoms: carryover, trips, low voltage, catalyst upsets, specification failures.

Most of this can be answered from drawings and operating records before a site visit.

Other clean-product duties

The same DC coalescer design is used to remove water or aqueous treating solutions from other low-conductivity products, such as gas condensate, liquefied petroleum gas (LPG), naphtha, jet fuel and diesel.

Talk to an engineer about your unit

Tell us the equipment, the duty and what you are seeing. Partial data is normal: send what you have and we will tell you what else matters. We acknowledge every enquiry within 1 working day.

Design parameters: Electrostatic coalescer prewash

Design parameters: Electrostatic coalescer prewash
ParameterTypical rangeUnitBasis / note
Electrode voltage20 to 40kV DCSustained continuously because kerosene has very low electrical conductivity.
Aqueous phase in treated keroseneParts per million levelppm by weightDesign target, set per project with the test method stated.
Operating pressureAbove the vapour pressure of the kerosenebargGauge pressure; follows the prewash contactor
Operating temperatureAs delivered by the prewash contactor°C
ConfigurationVertical or horizontalUsually a skid-mounted package with piping and local control panel
Insulation of entrance bushing and grid insulatorsPolytetrafluoroethylene (PTFE)

Typical ranges for orientation only. The design basis for each unit is set from the feed analysis and the required product specification.

Codes and standards applied to Electrostatic coalescer prewash

Typically applied; the governing codes are confirmed per project with the client and the jurisdiction.

ASME BPVC Section VIII Division 1
Pressure vessels Vessel design, where specified
PD 5500 / EN 13445
Unfired pressure vessels Where a UK or European code is specified
IEC 60079 / ATEX / IECEx
Equipment for explosive atmospheres Transformer and power unit, junction boxes, instruments
PED / UKCA / UKEX
Conformity marking Where the installation jurisdiction requires it

Applications: Electrostatic coalescer prewash

  • Caustic carryover removal: Separating entrained spent caustic from prewashed kerosene before the sweetening reactor, which protects the catalyst bed and limits fresh caustic make-up.
  • Sodium control in jet fuel: Reducing dispersed caustic so that downstream sodium and water-reaction limits in the jet fuel specification can be met.
  • Haze and water-separation protection: Lowering the aqueous phase so that the product can pass haze rating and water-separation tests after sweetening and clay treating.
  • Replacing an undersized settler: Restoring separation where a gravity settler or coalescer-media vessel no longer copes with higher throughput or a tighter dispersion.
  • Caustic settling after the reactor: Applying the same DC design on the reactor effluent where caustic settling is the limiting step.

Scope of supply: Electrostatic coalescer prewash

  • Process design and performance basis (From kerosene properties, flow rate, caustic strength and the outlet target)
  • Pressure vessel with inlet distributor, outlet collector, electrode grid, insulators and hangers (Fabricated by an approved and audited fabricator under our supervision)
  • Transformer and rectifier power unit, voltage controller, entrance bushing and high-voltage conductor
  • Interface level measurement and caustic draw-off control
  • Skid, interconnecting piping and local control panel
  • Flow distribution study by computational fluid dynamics (CFD) (For new internals and for retrofits of an existing vessel)
  • Commissioning, start-up support and operator training

Frequently asked questions: Electrostatic coalescer prewash

Why does caustic carry over from a kerosene prewash?

Caustic carries over from a kerosene prewash because mixing in the contactor shears the spent caustic into very fine droplets, and naphthenates formed in the prewash act as surfactants that stop the droplets merging. Gravity alone then needs more residence time than the settler provides, and the problem grows as throughput rises.

Why is a DC field used for kerosene rather than an AC field?

A DC field is used for kerosene because kerosene has very low electrical conductivity, so a steady field of tens of kilovolts can be held with little current. The steady field moves charged droplets towards the electrodes as well as polarising them, which suits a feed with a small aqueous fraction of very fine droplets.

What happens if caustic reaches the sweetening reactor?

Caustic and water reaching the sweetening reactor foul the catalyst bed, consume fresh caustic, and raise the sodium content of the product. Downstream, the jet fuel can fail haze, water-reaction or water-separation tests. Plants usually see the effect first as shorter runs between catalyst bed change-outs.

Can an existing electrostatic coalescer or precipitator be retrofitted?

An existing electrostatic coalescer or precipitator can usually be retrofitted. Axsia Howmar reviews the vessel, nozzles, electrode arrangement, bushings and power unit from drawings or a site survey, then designs replacement internals, bushings and power unit to fit the existing shell, including units whose original manufacturer no longer trades.

What information is needed to assess an installed unit?

To assess an installed unit we need the vessel data sheet or a nameplate photo, the nozzle schedule, any surviving drawings, the power unit rating and output voltage, design and current throughput, kerosene properties, caustic strength, the interface control arrangement and a description of the symptoms.

Talk to an engineer about your unit

Tell us the equipment, the duty and what you are seeing. Partial data is normal: send what you have and we will tell you what else matters. We acknowledge every enquiry within 1 working day.